The dehydration process of gypsum in the P T space was followed with Raman spectra collected along different isotherms and isobars up to 25 GPa and 633 K Temperature of the sample was varied at a rate less that 1°/min and soaking time was about 1 h Figure 1 reports the P T conditions where Raman spectra were collected Fig 1
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Get PriceDehydration of gypsum has been investigated in isothermal conditions within the 348 403 K range with a temperature increase of 5 K Dehydration proceeds through the CaSO4·2H2O → CaSO4· → γ CaSO4 steps Experimental data have been fitted with the Avrami equation to calculate the empirical activation energy of the process a is 109 12 kJ/mol
Get PriceIt has been determined that α hemihydrate gypsum can be obtained from FGD gypsum under hydrothermal conditions at 125 °C and 130 °C The compressive strength of gypsum samples is 13 MPa 16 MPa after 2 h of hardening and it depends on temperature and time of isothermic curing The compressive strength of the same samples
Get Pricein the high temperature and low water vapor pressure region gypsum dehydrates to form γ caso 4 in a single step process caso 4 ·2h 2 o → γ caso 4 with increasing water vapor pressure gypsum undergoes the caso 4 ·2h 2 o → γ caso 4 → β caso 4 · 2 o reaction path and as water vapor pressure increases further the occurrence of a two step …
Get PriceThis is not significantly higher than activation energies reported for the growth of gypsum 60 70 kJ/mol and does not support that slow dehydration rates of aqueous calcium is responsible for the well known difficulty to precipitate anhydrite crystals from supersaturated aqueous solutions at temperatures well above the anhydrite gypsum
Get PriceThis paper presents an experimental investigation of the sulfuration mechanism of concrete The microstructure mineral phase composition substance content and pH of the concrete were determined using scanning electron microscopy X ray diffraction comprehensive thermal analysis and pore solution pH test It was observed that light grey spots appeared on the surface of the specimen and a
Get PriceAn in situ dehydration kinetics study of gypsum under water saturated condition was performed in the temperature and pressure ranges of 383 423 K and 343 1085 MPa by using a hydrothermal diamond anvil cell and Raman spectroscopy Kinetic analysis shows that the dehydration rate k increases with pressure suggesting a negative pressure dependence on dehydration rate
Get PriceGypsum is a soft sulfate mineral composed of calcium sulfate dihydrate with the chemical formula CaSO 4 ·2H 2 O It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster blackboard or sidewalk chalk and drywall Alabaster a fine grained white or lightly tinted variety of gypsum has been used for sculpture by many cultures including Ancient Egypt
Get PriceDehydration of gypsum occurs from 100 to 150 ∘ C and is accompanied by an endothermic heat flow Water bonded to smectites is also expected to be released in this temperature range Jananee et al 2024 Combustion of soil organic matter can be identified through CO 2 release together with an exothermic heat flow
Get PriceÀ propos Currently employed as an engineer at Efectis France focusing in the fire safety expertise PhD degree in the University of Grenoble Alps with research focus on the behavior of concrete at high temperature Skilled in heat and mass transfer modeling of porous construction materials such as concrete and gypsum
Get PriceLaboratory experiments were carried out to explore defluoridation of drinking water using locally sourced gypsum and gypsum calcined at high temperatures A 400 u0001C calcined phase of gypsum gave the highest defluoridation capacity of % compared to raw uncalcined gypsum 200 300 and 500 u0001C calcined phases
Get PriceAfter the hydration is completed the excess amount of water needs to be evaporated to achieve the mechanical strength of the dihydrate crystals In the second stage the calcination of the formed dihydrate crystals was performed at 140°C for at least 4 hours to ensure the complete dehydration of dihydrate Table 1
Get PriceFigure 1 shows the DSC TGA profile for the dehydration of pure gypsum when heated at the rate of 5ºC/minute under the present investigation The parent weight loss curve indicates a single weight loss between 100 and 170º of DSC curve also does not resolute the two steps associated with the dehydration
Get PriceTo create the gypsum powder the raw gypsum is crushed and heat applied to drive off water and create a hemi hydrate Heating up the stone to disinfect it drives the water from the set stone and reduces it to the powder form The temperature at which it is safe to apply heat seems to be about 150°F or 66°C This is not a very high
Get PriceThe dehydration process of gypsum rock was studied under concentrated solar energy by using a Fresnel lens with power density of 260 Wcm −2 Temperatures higher than 700˚C were attained for 1 min of solar exposure The effect of grain size of sample and radiation exposure time on the formation of bassanite and anhydrite was studied by XRD
Get PriceThe temperature ranges of gypsum anhydrite and hemihydrate in the table are and K respectively All data above K were reserved for testing the extrapolation capabilities The criteria used to exclude or include a data point in the assessment are discussed in Section in detail Table 1
Get PriceA not for profit trade association founded in 1930 promoting the use of gypsum while advancing the development growth Standard time temperature curve Supplement to Construction Dimensions Magazine Gypsumation provides essential gypsum board information to A/E/C professionals contractors and code officials twice annually Receive your
Get PriceDepending on the mill temperature the gypsum becomes partially or completely dehydrated to hemihydrate or anhydrite respectively According to [8] the temperatures at which gypsum dehydration to hemihydrate can take place lie between 95 and 170 °C The results of [9] indicate that gypsum dehydration can even begin at temperatures below 70 °C
Get PriceCalcined gypsum is produced when dihydrate gypsum is fired at the temperature of 800 1100 °C At this time a little calcium sulphate is decomposed to generate new phase CaO which gives calcined gypsum certain hydrating ability The condensation speed of calcined gypsum is slow
Get PriceAdditional experimental challenges arise from the fact that under geological conditions dehydration occurs under a wide range of temperatures and pressures to name but the two most obvious relevant thermodynamic quantities The temperature gradient across the lithosphere is >1000˚C and its pressure gradient is on the order of several GPa
Get PriceIn this paper the effect of HPMC hydroxypropyl methyl cellulose ether on the cement mortar water retention WR and composition was studied The relationship between the plastic viscosity and water retention of cement mortar was revealed The results showed that HPMC formed a colloidal film with a 3D network structure in water which changed the ability of water to migrate The HPMC colloid
Get Pricesuitable to determine the water demand for gypsum hydration An excess of water is needed for good workability for the gypsum plasterboard production but a longer setting time is caused due to the high water amount 3 Void fraction of the gypsum is caused by the volume shrinkage during hydration and the evacuation of the excess water
Get PriceINTRODUCTION∗ temperature [4 6] The amount of minor and trace elements that can be DSC curves of samples hydrated for 28 days 1 200 °C the diffraction peaks characteristic for calcium silicate is mainly due to the dehydration of calcium silicate hydrates d spacing nm were
Get PriceThis article investigates the thermal performance of gypsum boards in the dehydration temperature region where pronounced chemical reactivity is anticipated Gypsum board samples were gradually heated up to 300°C using a low heating rate Temperature measurements at pre selected board locations indicated three distinct stages of gypsum dehydration free moisture evaporation transformation
Get PriceBoth room temperature and dehydration conditions were investigated for comparison In the pressure range investigated in the present study the dehydration of gypsum to bassanite H 2 O starts above 100 120°C [ Heard and Rubey Stress time curve for one initially dry intact sample G27C and corresponding temperature ramp
Get PriceThe temperature at the front is about 100 o C Dehydration is taking place since the hydration degree is lower than one Based on the temperatures this front can be attributed to the first dehydration reaction The first dehydration reaction releases 75% of the chemically bound water
Get PriceThe main reason for the high resistance of fire spreading through plasterboards is the dehydration phenomenon a chemical endothermic reaction occurring in the temperature range ≈90°C 250°C whereby the chemically bounded water contained in the gypsum crystal structure is released as vapour 1 2 The vapour is then driven by pressure and
Get PriceFGD gypsum can also be the limestone reacts with the SO2 and oxygen from air used in agriculture113 and can be treated to produce useful ultimately to produce calcium sulfate hydrate gypsum materials114 such as lime sulfur and which precipitates from solution in the sump Over 95% of the
Get PriceThe curve slope at this stage is 2 The slow descent stage 100°C 400°C The curve slope at this stage is 3 The rapid descending stage 400°C 700°C in which the slope of the curve is Based on these it seems that the brittle ductile transition of sandstone occurs at 400°C Figure 5
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